Tuesday, August 11, 2009

ORGANIC CHEMISTRY

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Introduction of Organic Chemistry

To understand life as we know it, we must first understand a little bit of organic chemistry. organisms.');">Organic molecules contain both carbon and hydrogen. Though many organic chemicals also contain other elements, it is the carbon-hydrogen bond that defines them as organic. Organic chemistry defines life. Just as there are millions of different types of living organisms on this planet, there are millions of different organic molecules, each with different chemical and physical properties. There are organic chemicals that make up your hair, your skin, your fingernails, and so on. The diversity of organic chemicals is due to the versatility of the carbon atom. Why is carbon such a special element? Let's look at its chemistry in a little more detail.

Carbon (C) appears in the second row of the periodic table and has four bonding -19 coulombs and a mass of 9.11 × 10-31 kg. Electrons are generally found around the nucleus of an atom, but may be gained or lost during ion formation. Compare to the proton.');">electrons in its 2O, oxygen has a valence of two; in CH4, carbon has a valence of four.');">valence shell (see our Periodic Table module for more information). Similar to other non-metals, carbon needs eight electrons to satisfy its valence shell. Carbon therefore forms four bonds with other atoms (each bond consisting of one of carbon's electrons and one of the bonding atom's electrons). Every 2 2s2 2p6 3s1; the 3s electron is the only valence electron in the atom. Valence electrons determine the chemical properties of an atom and are the only electrons that participate in chemical bonding.');">valence electron participates in bonding, thus a carbon atom's bonds will be distributed evenly over the atom's surface. These bonds form a tetrahedron (a pyramid with a spike at the top), as illustrated below:

carbon bonds - Carbon forms 4 bonds

Carbon forms 4 bonds

Organic chemicals get their diversity from the many different ways carbon can bond to other atoms. The simplest organic chemicals, called hydrocarbons, contain only carbon and hydrogen atoms; the simplest hydrocarbon (called methane) contains a single carbon atom bonded to four hydrogen atoms:

carbon-methane - Methane - a carbon atom bonded to 4 hydrogen atoms

Methane - a carbon atom bonded to 4 hydrogen atoms

But carbon can bond to other carbon atoms in addition to hydrogen, as illustrated in the molecule ethane below:

carbon-ethane - Ethane - a carbon-carbon bond

Ethane - a carbon-carbon bond


Simple Hydrocarbons
The simplest hydrocarbons are those that contain only carbon and hydrogen. These simple hydrocarbons come in three varieties depending on the type of carbon-carbon bonds that occur in the molecule. Alkanes are the first class of simple hydrocarbons and contain only carbon-carbon single bonds.
The chemical formula for any alkane is given by the expression CnH2n+2.The alkanes are named by combining a prefix that describes the number of carbon atoms in the molecule with the root ending "ane". The names and prefixes for the first ten alkanes are given in the following table.